Why doesn’t Bing Discover button work ? This content is blocked. Contact the site owner to fix the issue“
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If you are experiencing an issue with the new Bing icon in the Microsoft Edge browser’s toolbar, some of the primary causes of this issue could be: Usage of VPN or security software features interfering with the browser. To fix the issue, you need to eliminate the possibilities of the error one by one.

Solved : The content is blocked error when using Bing button on Edge
1- Disable the VPN by going to the VPN application you are using on your PC.
2- If you have Kaspersky, go to Settings > Network settings > Traffic Processing, and uncheck “Inject script into web traffic to interact with web pages“.

Click Save to save the changes.
That’s all.